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Chem 120 EXPERIMENT 8 Double Displacement Reactions

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Introduction

Double displacement reactions are among the most common simple chemical reactions and com-

paratively easy to study. In each part of this experiment two water solutions, each containing posi-

tive and negative ions, will be mixed in a test tube. Consider the hypothetical reaction:

AB (aq) + CD (aq) AD (?) + CB (?) (EQ 8.1)

where AB (aq) exists as A+

(aq) and B-

(aq) ions in solution and CD (aq) exists as C+

(aq) and D–

(aq) ions

in solution. As the ions come in contact with each other, there are six possible combinations that

might conceivably cause a chemical reaction. Two of these combinations are the meetings of ions

of like charge; that is A+

(aq) + C+

(aq) and B-

(aq) + D–

(aq). Since like charges repel, no reaction will

occur. Two other possible combinations are those of the original two compounds; that is, A+

(aq) +

B–

(aq) and C+

(aq) + D–

(aq). Since we originally had a solution containing each of these pairs of ions,

they can mutually exist in the same solution; therefore they do not recombine. Thus the two possi-

bilities for the combination of each of the positive ions with the negative ion of the other compound

is: A+

(aq) + D–

(aq) and C+

(aq) + B–

(aq).

In order for a double displacement reaction to occur one or more of the following must happen:

1. A precipitate is formed.

2. A gas is produced.

3. Water or another slightly ionized substance is formed

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